Metal Gear Solid: Peace Walker HD Trophy Guide & Road Map

Metal Gear Solid: Peace Walker HD
Metal Gear Solid: Peace Walker HD Trophy Guide

Section 01. Overview

Estimated Trophy Difficulty: 5.0 (Estimated for now)
Offline Trophies: 46 (37, 8, 1)
Online Trophies: 4 (2, 1, 1)
Approximate time to /100%: 80+ Hours
Minimum Number of Playthroughs Needed: 1+ (Game is open ended and will require numerous playthroughs of various missions)
Number of Missable Trophies: 0
Glitched Trophies: None
Does difficulty affect trophies: No
Do cheat codes disable trophies: No

Section 02. Introduction

Metal Gear Solid: Peace Walker HD is an upscale from the game that came out in 2010 on the PSP. Peace Walker HD is also only available on the NA and EU version of the game, the JP version came with the original Metal Gear Solid instead. Being a port of a PSP game there are a number of things that are different from the main Metal Gear Solid games. The two big ones are the controls are slightly different and the other is that the entire game is open ended and mission based. Earning the platinum trophy isn't difficult but will require dedication and a time commitment.

Section 2.1 - What you need to understand

You will need to collect staff for your base with high ranking skills. They are paramount to earning your platinum as they allow the creation of gear and will perform combat in the OUTER OPS. The most frustrating part of this is to get the highest ranking staff you'll need to complete some of the most difficult missions (5 red skulls), these missions will also be required to obtain the gear that's paramount to earning all S Ranks. Lastly you can play through most of the missions (MAIN/EXTRA OPS) with up to 3 other people to gain camaraderie, however doing so will make the missions more difficult with each partner you bring in.

WARNING: For you veterans out there who played a lot or even mastered this game on the PSP I have some bad news for you. You may have noticed the game will let you transfer data from your PSP; you cannot earn trophies on a file you started on your PSP. You can start a file on the PS3 and transfer it to the PSP, then transfer the file back and earn trophies for whatever actions you performed on the PSP. However there is a chance the game may not give you the trophies for your actions on the PSP, so I would advise to play the game in its entirety on the PS3.

Section 03. Walkthrough

The way this game is setup there is no real way to do a walkthrough. Once you clear all the MAIN OPS there's only the OUTER OPS and EXTRA OPS. Both mission sets unlock as you progress through the MAIN OPS and their own separate missions but unlike the MAIN OPS they do not unlock in numerical order. The biggest problem is the game requiring you to go through some of the toughest fights with less than ideal gear.

Section 3.1 - MAIN OPS / Initial Playthrough

This will be going through the MAIN OPS and whatever EXTRA OPS you feel like doing. You'll have a few vehicle battles and fight the first incarnation of all the AI weapons and finish up the story. This is only the beginning of your road to the platinum. You can play most of the missions online to get a jump start on the trophy that requires gaining camaraderie.

Trophies Earned
An Army Without Borders
A Country Without An Army
The Phantom Hero
A Nation Reborn
The Illusion of Peace
Outer Heaven
Launched ZEKE
Basilisk Eater

Section 3.2 - EXTRA OPS / Force Build Up

This will be going through the EXTRA OPS and bolstering your forces. You'll need to start working on the EXTRA OPS and collecting talented staff members; you should also have strong enough staff to start working on the OUTER OPS missions as well. This is where most of your time will be spent, grinding missions over and over to get staff and going through all the missions to unlock the gear you will need to make the S Rank on missions. Keep in mind you can work together with a partner through co-op to gain camaraderie as you do this.

Trophies Earned
Bronze Trophy Deliverer
Fulton Recovery Veteran
Hold-Up Artist
Lethal Enforcer
Stun Specialist
Hideo Kojima
Mech Catcher
Paz's Thoughts
Huey's Thoughts
Strangelove's Thoughts
Monster Hunter
CQC Six Shot
Leap of Faith
I feel... safe
Indirect Attack
OUTER OPS Sortie
That Looks Tasty!
Divine Wind
You have far too many Game Overs
Don't you have anything else to do with your time?
Kuwabara, Kuwabara
I'm dead serious
You're pretty good
Special Staff Recruiter
Elite Forces
Gives me infinite ammo
Stealth camouflage
Completed ZEKE
Steel Eater

Section 3.3 - MAIN/EXTRA OPS S-Rank

This will be the result of all the effort you put into the previous step. When you have the sufficient gear and skill you'll want to S-Rank all 32 MAIN OPS and all 128 EXTRA OPS. When this is over you'll be almost done and with most of the game behind you. You can also team up for these trophies to work towards your camaraderie score, just remember it will make the mission harder.

Trophies Earned
Bronze Trophy Paz Mania
Kaz Mania
Costume Collector
MAIN OPS All Rank A
EXTRA OPS All Cleared
EXTRA OPS All Rank A
MAIN OPS All Rank S
EXTRA OPS All Rank S
Big Boss

Section 3.4 - Online Trophies

Earning the few online trophies will not take long compared to the time you spent building your forces. The longest will just be earning 20,000 camaraderie if you have yet to do it while playing the missions.

Trophies Earned
Trader
VERSUS OPS All Rules
Vic Vos

Section 3.5 - Cleanup

If there's anything you missed or still need to accomplish now is the time to do it. By the time you earn an S-Rank in all the missions there isn't much to do and so any cleanup you may need to do should be short. If there's nothing to clean up then you'll have a new shiny platinum in your collection.

Trophies Earned
Platinum Trophy Vic Boss

[PS3T Would Like to Thank Kheapathic for this Roadmap]

Vic Boss

Obtained every trophy.
(15)
MAIN OPS All Rank A

Cleared all MAIN OPS at Rank A or higher.
This trophy requires you to clear all 32 MAIN OPS missions with an A or S rank. You can mix solo and co-op play as long as you clear every mission with an A or S rank.

See S-Rank Guide for details.
MAIN OPS All Rank S

Cleared all MAIN OPS at Rank S.
(2)
This trophy requires you to clear all 32 MAIN OPS missions with an S rank. You can mix solo and co-op play as long as you clear every mission with an S rank.

See S-Rank Guide for details.
EXTRA OPS All Cleared

Cleared all EXTRA OPS missions.
(1)
This trophy requires you to clear all 128 EXTRA OPS missions. You can mix solo and co-op play as long as you clear every mission, your ending rank doesn't matter either.
EXTRA OPS All Rank A

Cleared all EXTRA OPS missions at Rank A or higher.
(1)
This trophy requires you to clear all 128 EXTRA OPS missions with an A or S rank. You can mix solo and co-op play as long as you clear every mission with an A or S rank.

See S-Rank Guide for details.
EXTRA OPS All Rank S

Cleared all EXTRA OPS missions at Rank S.
(13)
This trophy requires you to clear all 128 EXTRA OPS missions with an S rank. You can mix solo and co-op play as long as you clear every mission with an S rank.

See S-Rank Guide for details.
Big Boss

Cleared all MAIN OPS and EXTRA OPS missions at Rank S.
(1)
This trophy requires you to clear all 32 MAIN OPS and 128 EXTRA OPS missions with an S rank. You can mix solo and co-op play as long as you clear every mission with an S rank.

See S-Rank Guide for details.
Fulton Recovery Veteran

Reached 300 Fulton recoveries.
This trophy requires you to recover 300 enemy soldiers with any Fulton recovery gear; Fulton Recovery, Fulton Recovery Mine or C.Gustav (FR). The game only remembers recoveries made after a completed mission, any recoveries made in a mission you fail do not count. Simply keep using the recovery system on enemy soldiers and this trophy will pop after you extracted enough enemies.
Hold-Up Artist

Reached 100 hold-ups.
(4)
This trophy requires you to hold-up 100 enemy soldiers. To hold up an enemy soldier sneak up on them from behind and hold when you get close; Snake will say "Freeze!" and the enemy will lie down on the ground. From here you can loot them for items/ammo or use the Fulton recovery system. The game only remembers hold-ups made after a completed mission, any hold-ups made in a mission you fail do not count. You cannot hold up an enemy during an ALERT phase, upon being discovered in a vehicle mission or at all in a strictly combat mission.
Lethal Enforcer

Reached 100 kills.
(3)
This trophy requires you to kill 100 enemies. Simply use any lethal weapon and kill enemies until you've killed 100 of them. The game only remembers kills made after a completed mission, any kills made in a mission you fail do not count.
Stun Specialist

Reached at least 100 stun attacks or sleep-inducing attacks.
This trophy requires you to knock an enemy unconscious or put them to sleep. You can use CQC, Stun Rod, Mk. 22, Moisin Nagant, Sleep Grenades or the Fulton Mine. Reach a total of 100 enemies you've knocked out or put to sleep to earn this trophy. The game only remembers unconscious enemies made after a completed mission, any unconscious enemies made in a mission you fail do not count.
Costume Collector

Obtained every costume.
(4)
To earn this trophy you will need to collect every uniform in the game. Some are awarded for completing missions, S-Ranking missions or finding the uniform in a mission. The game doesn't record you finding the uniform until you've completed the mission you earned it in. You will earn this trophy at the mission results screen.

Uniform List

Sneaking - Complete MAIN OPS - Attack Chopper Battle: MI-24A.

Battle - Complete MAIN OPS - Peace Walker Battle.

Battle W/H - Complete any OUTER OPS with a difficulty of S+.

J.Fatigues - Default

Leaf - S-Rank EXTRA OPS 014.

T.Stripe - MAIN OPS - Puruse Amanda, search Banana Fruta De Oro.

Choco-Chip - S-Rank EXTRA OPS 045.

Auscam - MAIN OPS - Destroy the Barricade, search Aldea Los Despiertos.

Squares - Search Banana Fruta De Oro in EXTA OPS 030.

Splitter - Find the uniform on a crate in EXTRA OPS 029, use a box drop to reach it.

Snake - MAIN OPS - Travel to Cloud Forest, search Selva del la Leche: Hillside.

Neo-Moss - Use your codec near the first ghost in EXTRA OPS 062 until you hear "This is The End" then complete the mission.

Stench - S-Rank EXTRA OPS 061.

Tigrex - S-Rank EXTRA OPS 123 - 124.

Rathalos - S-Rank EXTRA OPS 121 - 122.

Gear Rex - S-Rank EXTA OPS 125 - 126.

Naked - Default

NKD(Leaf) - Awarded with the uniform Leaf.

NKD(Tiger) - Awarded with the uniform T.Stripe.

NKD(Choco) - Awarded with the uniform Choco-Chip.

NKD(Ausy) - Awarded with the uniform Auscam.

NKD(Sqrs) - Awarded with the uniform Squares.

NKD(Split) - Awarded with the uniform Splitter.

NKD(Snake) - Awarded with the uniform Snake.

Tuxedo - Complete MAIN OPS - Peace Walker Battle 3.

Amanda - S-Rank EXTRA OPS 067. (Female only)

Miller - S-Rank EXTRA OPS 068. (Male only)

Bikini - Complete all MAIN OPS and EXTRA OPS. (Female only)

Swim Trnks - Complete all MAIN OPS and EXTRA OPS. (Male only)

T-Shirt - Search EXTRA OPS 001.

R.Commando - Complete EXTRA OPS 037. (Male Versus only)

R.Soldier - Complete EXTRA OPS 024. (Male Versus only)

Scout - Complete EXTRA OPS 061. (Male Versus only)

Guard - Complete EXTRA OPS 038. (Male Versus only)

Commando - Complete EXTRA OPS 009. (Male Versus only)

M.POW - Complete EXTRA OPS 052. (Male Versus only)

F.POW - Complete EXTRA OPS 055. (Female Versus Only)

Patrolman - Complete EXTRA OPS 011. (Male Versus only)

Mechanic - Complete EXTRA OPS 066. (Male Versus only)

Escort - Complete EXTRA OPS 027. (Male Versus only)

Black - Default

Khaki - Default

Navy Blue - Default

White - Default

Red - Default

Yellow - Default

Pink - Default

Green - Default

Water - Default

Tree Bark - Default

DPM - Default

Comrade - Default

G&J - Default

NKD(Black) - Default

NKD(Khaki) - Default

NKD(N.Blu) - Default

NKD(White) - Default

NKD(Red) - Default

NKD(Yelw) - Default

NKD(Pink) - Default

NKD(Grn) - Default

NKD(Watr) - Default

NKD(T.B) - Default

NKD(DPM) - Default
Special Staff Recruiter

Assembled all special staff members.
(8)
This trophy may be misleading at first glance; there are several staff members in your force with UNQ (unique) next to their name, but this trophy does not pertain to them. There are four characters in the game who have special jobs; one of them has a unique name while the other three have the generic animal code name. You will have to use Fulton recovery to get the three generic staff as they are POW's. This trophy will pop at the end of the mission after recovering the fourth member.

Special Staff

Hideo Kojima
This is the only specially named staff member for this trophy. In the MAIN OPS mission Infiltrate Crater Base you'll be tasked to search various trucks at the end of the mission. Search the truck with the license plate 63284 to find and rescue Hideo Kojima.

New Voice Actor
In MAIN OPS mission Zadornov Search 1 he'll be a randomly placed POW in an area. Use Fulton recovery on him then finish the mission.

Veteran Voice Actor
In MAIN OPS mission Zadornov Search 5 he'll be the only POW in the entire area. Use Fulton recovery on him then finish the mission.

Actress
In MAIN OPS mission Travel to the Mine Base; go up the first ladder to your left. Hang off the side of the building to your left and shimmy along to the other side of the building to her. Use Fulton recovery on her then finish the mission.
Hideo Kojima

Recruited Hideo Kojima.
(4)
This must be done in the MAIN OPS mission Infiltrate Crater Base. On the last part of the mission you'll have to search various trucks. Search the truck with the license plate 63824 and you'll find Hideo Kojima. You'll earn this trophy at the end of the mission.
Mech Catcher

Captured a mech.
There are 4 types of mechs in the game; LAV, BTR, Tank and Helicopter. All you need to do is capture one but it's a bit trickier then it sounds. Instead of going into it in detail here, please check the S-Rank Guide for specific details.
Paz's Thoughts

Read all of Paz's diary.
(1)
Paz has 10 diary entries to read through and you can only get them from fighting the AI Weapons second and third incarnations (EXTRA OPS 112 - 119). When you're in the AI pod and removing memory boards and moving between the four rows you may see appear at the bottom of the screen for a moment. Press to obtain a tape of Paz's diary, do this 10 times in any AI fight to collect all her diaries. After collecting 10 of them go into a mission briefing and go to the additional information to find Paz's diary. Listen (or scroll through) all 10 of her diary entries to earn this trophy.
Huey's Thoughts

Read Huey's love letter.
(1)
Huey gives you his love letter in Chapter 4. You can read it by selecting the Other tab under the R&D option at Mother Base. It's simply labeled as "Letter," press to read it and earn this trophy.
Strangelove's Thoughts

Read all of Strangelove's memoirs.
Strangelove has 3 memoirs that are easy to collect. After clearing Chapter 5 go back to any of the first incarnations of the AI weapons. When you're in the AI pod and moving between the columns of memory boards you may see a appear at the bottom of the screen for a moment. Press to obtain a tape of Strangelove's memoirs, do this 3 times in any first level AI fight to collect her memoirs. After collecting all 3 of them go into a mission briefing and go to the additional information to find her memoirs. Listen (or scroll through) all 3 of her memoir entries to earn this trophy.
Monster Hunter

Cleared all hunting quests.
(8)
There are 8 hunting quests (EXTRA OPS 121 - 128) that need to be cleared for this trophy. To unlock these missions you need to be at the end of Chapter 4 and in the missions briefing menu listen to all of Chico's tapes (or you can scroll through them). After listening to all his tapes go to EXTRA OPS 029; after blowing up the target and collecting the items go to Playa del Alba approach the cat in the boat at the end of the dock. At the end of the conversation you will unlock EXTRA OPS 121, clear each hunter mission to unlock the next one. Clear all 8 hunter missions to earn this trophy.
CQC Six Shot

Performed CQC six times in a row.
(11)
To get this trophy you must do a continuous string of 6 CQC attacks. In EXTRA OPS 024 you'll have to defeat 15 enemy soldiers. The first three should be taken care of easily, now from where you started turn around and jump down to the ground. The next 6 enemies will come from the big tunnel. Don't get too close otherwise some of the enemies will run back across the area of operations line which will make them unavailable to hit. While the enemies are still grouped up use the CQC throw and tap to do a continuous string of attacks. If you fail on the first group, the next group of 6 enemies spawn where the first 3 spawned so you can try on them without restarting the mission.
Leap of Faith

Performed a Leap of Faith.
(3)
To get this trophy go to MAIN OPS "Travel to the Mine Base." The biggest building near the exit of this area has a bale of hay at near one side of it. Climb to the top of the building and find the pile of bird poop (it's a white splotch). Stand in the bird poop and Kaz will mention assassins and you'll be prompted to dive into the hay. Press to jump into the hay bale to get the Assassin's Box and this trophy.
I feel... safe

Wearing a cardboard box gives you that feeling of inner peace.
(7)
There are various versions of boxes in the game. Go into any mission and equip one of the boxes and don't move to earn this trophy.
Indirect Attack

Attacked enemy soldiers by blowing up an oil drum or truck (single player only).
(1)
In various missions there are oil drums and vehicles you can shoot to blow up. This trophy is made very easy by EXTRA OPS 056. In this op you need to kill 5 enemies with one bullet by shooting an explosive barrel. Killing just one of them with the explosive barrel is enough to earn this trophy.
OUTER OPS Sortie

Carried out a mission in OUTER OPS.
You'll have to play a few MAIN OPS missions to unlock the OUTER OPS option in Mother Base. Once it opens up you can send up to 8 staff of your combat unit into a battle. Once you make the squad and commit them to the mission, go complete your own mission. After your mission go back to OUTER OPS to receive the debrief of your unit and earn this trophy.
Elite Forces

Cleared 'Capture the Enemy Base 06' in OUTER OPS using only soldiers.
(2)
This trophy is actually quite easy if you are prepared properly. This is the final OUTER OPS mission and is only unlocked by completing all other missions first. Your first order of business is getting combat staff with the highest marks in all combat skills and then having their abilities raised until their Health and Psyche are both at 9999. Your second order of business is to research the best weapons available, as your OUTER OPS troops will be using whatever you research. To make this mission easy, have the M47 and K.Pistol researched and your troops will be able to easily take down the enemies. Set 8 of your best combat staff on the mission and go do your own mission; afterwards watch the results of the OUTER OPS and if your forces win you'll earn this trophy.
Trader

Carried out a trade.
(100)
Go into the Staff option and put your potential staff trades into the Trade Waiting Room. Now go into the Trade option and host or search for a trade partner. Once you find one you can choose which of their staff you want while they choose your staff that they want. Once the both of you finalize the trade you'll earn this trophy. Keep in mind that you can only trade staff members across specialty but they must be of equivalent skill. That is a staff of A, B, C, D or E rank must be traded for another one of the same rank; while their specialty (combat, medic, cook, r&d, intel) doesn't matter.
Deliverer

Sent an item using Delivery.
This trophy may sound like it requires online but it doesn't. Go into the Delivery option and then Create New Gift; set the address to free and put whatever items you want into the box then send it out to earn this trophy.
Paz Mania

Obtained Rank S on a date with Paz.
(1)
This is EXTRA OPS 067 and becomes available near the end of Chapter 5. This mission is easy but requires a good amount of preparation. This mission doesn't require much except the "Tuxedo" uniform and "Love Box" item. In the mission preparation screen you'll need to change your co-op messages to affirming phrases. Once the mission starts stand near Paz and throw out one of the co-op messages. If you see a heart appear over her head it means her affection is growing; each heart raises her affection by 10. You have to wait between phrases for the next one to work on her. Each positive phrase can be used twice to raise her affection. You can also use the Walkman to raise her affinity by playing the song "Koi No Yokushi Ryoku." Another way to raise Paz's affection is to use the camera and take pictures of her in different poses. Once her affinity reaches 200 equip the love box and stand near her, Paz will then join Snake under the box and the mission will end. As long as her affinity reached 200 you'll earn an S Rank and this trophy.

Positive phrases

I'm with ya.
Follow me!
Peace!
Good!
Impressive.
Good to have you.
Good luck.
Thanks.
Sorry...I just...
Nice one!
I knew you had it in you!!
Not bad!
Kept you waiting, huh?
Don't die on me.
I like it!
You can do this
Kaz Mania

Obtained Rank S on a date with Kaz.
This is EXTRA OPS 068 and becomes available after clearing EXTRA OPS 119. The preparation for this mission is exactly the same as the date with Paz. Kaz doesn't respond to all of the same phrases Paz does, but he doesn't require as much affection as she does. On top of positive phrases you can raise his affection by CQC throwing him. Once you've raised his affection to 100, equip the love box and stand next to him until he joins you to finish the mission. As long as his affection is at 100 you'll earn an S rank on this mission.

See Paz Mania for positive phrases.
That looks tasty!

Nicely cooked a ration.
(2)
This can only be done in EXTA OPS 121 - 126. During your fight with the monsters approach the fire pit with a ration equipped and press to sit down at the fire. Snake will put a ration on the spit and cook it. The moment it turn brown, press to get a Well Done Ration and this trophy.

See Monster Hunter on how to unlock EXTRA OPS 121+.
VERSUS OPS All Rules

Played using all of the rules in VERSUS OPS.
(39)
This trophy is worded improperly and only requires you to play the 4 game types; Deathmatch, Team Deathmatch, Capture and Control. As long as you complete a full round of each game type you'll earn this trophy at the end of the last game type. This trophy can be expedited with a boosting partner and setting your game options to minimum time limits and minimum game rounds.
Divine Wind

Collected a soldier using a divine wind.
(16)
This can only be done with the Tanegashima Musket. To get this weapon you must get the item Rathalos Wing from EXTRA OPS 121 or 122. This item is a very rare drop and it may take you a lot of mission clears to get it. Now with the Rathalos Wing you need a member of your R&D team to have the Japanese Patriot skill. You can find an A Rank R&D POW with this skill in EXTRA OPS 049. With both of these you can research the Tanegashima. When it's finally made go into a mission and use it to shoot enemies. Eventually it will hit an enemy with a whirlwind that will automatically fulton recovery them and give you this trophy.

There is a way to increase the odds at which the Wing drops, but it still may take multiple runs to see the item drop. First you must fight Rathalos on his second level EXTRA OPS 122. You must destroy both wings, his head and his tail. You must also use a non-lethal kill against him. The tail drop base is about 3% and doing all the above should raise it to almost 30%.

An Army Without Borders

Cleared Prologue: An Army Without Borders.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Investigate the Supply Facility.
A Country Without An Army

Cleared Chapter 1: A Country Without An Army.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Pupa Battle.
The Phantom Hero

Cleared Chapter 2: The Phantom Hero.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Chrysalis Battle.
A Nation Reborn

Cleared Chapter 3: A Nation Reborn.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Peace Walker Battle.
The Illusion of Peace

Cleared Chapter 4: The Illusion of Peace.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Peace Walker Battle 3.
Outer Heaven

Cleared Chapter 5: Outer Heaven.
(1)
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Metal Gear ZEKE Battle.

Reaching the Metal Gear ZEKE battle may be confusing for some. After clearing Chapter 4 you're in Chapter 5 but the game is very tight lipped about how to proceed. So here is a list of things to do to progress the storyline.

#1. Complete EXTRA OPS missions until Kaz tells you that Zardonov has escaped. You will now have a MAIN OPS mission to go recapture Zadornov. This will happen 6 times, yes Zadornov will escape and you will have to recapture him 6 times.

#2. You'll have to get all parts on Metal Gear ZEKE, which is a requirement for the trophy Launched ZEKE.

#3. With a completed Metal Gear ZEKE go complete more mission until Zadornov escape for his seventh time. However this time there is no MAIN OPS mission to go recapture him. Head to EXTRA OPS 001 and when you enter the area you'll hear Zadornov laugh. Go up to the second level and search for him; after finding him you'll unlock the MAIN OPS mission Metal Gear ZEKE Battle.
You have far too many Game Overs

Reached 50 or more game overs.
(7)
This is easy enough to pull off. Simply fail missions and reach the game over screen 50 times. Do this by getting killed or failing specific mission objectives. This trophy will pop at the Game Over screen.
Don't you have anything else to do with your time?

Rolled 100 times or more in a single mission.
(2)
This is as simple as it sounds. Select any mission and perform a roll 100 times in a single mission to earn this trophy.
Gives me infinite ammo

Acquired Infinity Bandana. Never worry about running out of bullets ever again.
(4)
To first unlock the bandana for research you will need to S-Rank EXTRA OPS 119. Once that is done you can research the bandana if your Combat level is 88 and your R&D level is 88. Fully research the item to get the bandana and this trophy.
Stealth camouflage

Acquired stealth camouflage. Never worry about being detected ever again.
(5)
To first unlock the stealth for research you will need to S-Rank EXTRA OPS 050. Once that is done you can research the stealth if your Intel level is 88, your R&D level is 88 and you have a R&D member with the Metamaterials skill. You can find an A-Rank R&D with the appropriate skill as a POW in EXTRA OPS 049. Fully research the item to get the stealth and this trophy.
Kuwabara, Kuwabara

Heard a ghost on the radio.
(10)
This can only be done on EXTRA OPS 062. Go to the first item and standing near the ghost, use your codec until you hear a ghastly message and this trophy will pop. This can only be done at the first ghost in the mission, none of the other ghosts will be heard.

Note: This ghost is also required to get the Neo Moss uniform. Keep using the Codec until you hear the message "This is The End." Now finish the mission to earn the uniform.
I'm dead serious

Threw a chaff grenade at ZEKE (single player only).
(6)
This can only be done in the MAIN OPS mission Metal Gear ZEKE Battle. Be sure your ZEKE has the Radome attached and you have chaff grenades in your equipment before you begin this mission. Once the mission starts, throw a grenade at it to earn this trophy.
You're pretty good

Shot enemy right in the middle of the rear end.
(5)
This is an easy trophy to pull off. Get behind an enemy and aim directly between the pockets on their pants and shoot. You'll know you hit the proper area if you score a critical hit on them; lethal weapons and non-lethals will put them down in one hit.
Launched ZEKE

Complete Metal Gear ZEKE.
(5)
This trophy may take a while to earn. To complete ZEKE you need to equip the 4 main parts and the 4 optional parts of ZEKE. Then go into a mission and afterwards you should get a message from Huey who will say ZEKE is complete and you'll earn this trophy.

ZEKE Parts

To get the four main parts you'll need to fight the AI weapons until you get enough scrap to craft all four parts.

Three of the four AI weapons carry the optional parts you'll need. If you damage the parts too much you'll lose your chance of getting them at the end of the battle. Focus on shooting the AI pod to destroy the weapon. The part drops are not guaranteed either, you may need to replay the missions multiple times to get the parts.

The Jet Pack is dropped by the Pupa AI; do not shoot the engines on the sides of the weapon.

The Radome and Railgun are dropped by the Chrysalis AI; do not shoot the Radome or Railgun.

The Armor is dropped by the Cocoon AI; just focus on shooting the AI pod
Completed ZEKE

Customized ZEKE's head parts and foot parts with special AI weapon parts.
(8)

You will need to have EXTRA OPS 112 - 119 unlocked to do this. Each 3rd Tier AI weapon has a small chance to drop their head unit after the battle, if you don't damage it too much. You will need to have at least one of these special head units. The 2nd and 3rd Tier Peace Walker has a small chance to drop its legs unit after the battle, if you don't damage it too much. Equip ZEKE with one of the AI heads and the Peace Walker legs for this trophy.
Vic Vos

Reached a total of 20,000 or more Camaraderie.
(232)
This trophy requires you to play online in either Versus or Co-op. Each mission or match you clear awards you with camaraderie. This is easy to grind with a partner in Versus play by setting each round to the minimum time and just playing for a few hours at a time. This can also be easily obtained by playing through the MAIN/EXTRA OPS with a partner or two. By the time you're ready to work on the S-Ranks you'll already have plenty of camaraderie.

Warning: It is possible to lose camaraderie by playing with too many random people. The game only records the last 50 people you've played with. If you play with more then 50 people the game will start pushing the latest name on its memory off and erasing all the camaraderie you had with that player.
Basilisk Eater

Defeated Pupa, Chrysalis, Cocoon, Peace Walker.
This trophy is storyline related and cannot be missed. You'll earn this trophy after you complete the MAIN OPS mission Peace Walker Battle 2.
Steel Eater

Defeated all AI weapons.
(1)
You will need to have EXTRA OPS 112 - 120 unlocked to do this. You will need to destroy all 3 tiers of each AI weapon and defeat AI ZEKE. Your ranking after each fight doesn't matter as long as you complete each mission. You will earn this trophy at the mission results screen of your final AI fight.