Find the grey blimp icon on the map, and web rush to the pole sticking out of the front. The man inside will give you a challenge; either a video or race challenge. Complete all of the video challenges to unlock this trophy.
For the video challenges, you must move the camera in order to keep Spider-Man centred and the crosshairs glowing green. These are fairly straightforward, and shouldn’t require too many attempts.
You’ll need to play through most, if not the entire storyline, before all of these are unlocked.