Whilst playing through the game, you will be informed about a robbery taking place in the St. Gabriel Bank, and a blue dollar sign icon will appear on your map. Travel here and complete the level, defeating Felicia Hardy at the end, and this trophy will unlock.
Felicia is good fun to fight, mostly because of the dialogue. At the beginning, web shoot her as she fires her guns at you until she can’t move. Then close in for a combo or two before retreating out of the way.
Repeat this until she throws down a flashbang and hides. Get onto a wall and crawl around until you find her hiding behind a pillar, and web strike into her. (You can’t run around looking for her as she disappears as soon as she sees you otherwise). Rinse and repeat, and Ms. Hardy will be defeated before you know it.