Story related, unmissable.
Defeat the three Hunter robots in Chapter 4: To Smash a Spider to unlock this trophy. You will fight one Hunter, followed by two more, but the tactics to defeat them remain the same.
To dodge the Hunter’s attacks, web rush side to side to avoid the blue energy balls that it fires, and press repeatedly to get out of the way of its energy dome, which damages you all the time you are inside.
Chase the Hunter, and press when prompted to kick it into the ground. Repeat this four times, and complete the quick-time event (press quickly) to smash the Hunter.
You can also use to web shoot the Hunters and slow them down.